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Derive Bragg Law. Explain why X rays and not Y rays are used for structure analysis.What data about the crystal structure can be obtained from the X ray diffraction pattern of crystal

Mumbai university > FE > SEM 1 > Applied Physics 1

Marks: 7M

Year: May 2013

1 Answer
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Consider a regular arrangement of atoms with inter-planar distance "d". An X-ray beam is incident upon the surface at glancing angle "θ"

Let us assume that the path difference between the scattered rays BC and EF as ∆=nλ thus producing constructive interference.

Now,

∆ = PE + EQ

∴ ∆ = BE.sin θ + BE.sin θ

∴ ∆ = 2BE.sin θ

∴ ∆ = 2d.sin θ

But, ∆ = nλ

∴ nλ = 2d.sinθ

This, is the required expression for Bragg's Law

Why X-Rays are used:-

  • Crystal structure is analyzed by using the diffraction pattern found after an electromagnetic wave is incident upon it.

  • In order to get a regular diffraction pattern, the incident wave should have a wavelength comparable to the dimension of the object being observed.

  • The dimensions of atom are of the order 10-10 m, which is comparable to the wavelength of X-ray.

  • Hence, X-rays and not γ-rays are used to analyze crystals.

From the X-ray diffraction pattern, the inter-planar spacing can be obtained using Bragg’s Law

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