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Short note : Clausius inequality.
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  • The second law of thermodynamics often leads to expressions that involve inequalities; one of them is the Claussius inequality.

  • It states that, the cyclic integral of $\frac{dQ}{T}$ is always less than or equal to zero. This inequality is valid for all cycles, reversible or irreversible. i.e $\oint\frac{dQ}{T} ≤ 0$

  • Any heat transfer to or from a system can be considered to consist of differential amounts of heat transfer. Then the cyclic integral of $\frac{dQ}{T}$ can be viewed as the sum of all these differential amounts of heat transfer divided by the temperature at the boundary

  • The equality in the Clausius inequality holds for totally or just internally reversible cycles and the inequality for the irreversible ones.

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