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Define Gibbs phase rule.

Mumbai University > First Year Engineering > Sem1 > Applied Chemistry 1

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Statement – if the equilibrium of a heterogeneous system is not influenced by gravitational, electrical or magnetic forces or by surface action but only by temperature, pressure and concentration , then the number of degrees of freedom of the system is related to the number of components and phases by the phase rule equation-

$$F=C-P+2$$

For any system at equilibrium at definite temperature and pressure.

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