0
423views
Find out critical radius ratio of an ionic crystal in ligancy 6 configuration. What is maximum size of cation in ligancy 6 configuration when radius of anion is 2.02 A
1 Answer
0
3views
written 3.5 years ago by |
In given arrangement, the cation is extracted into 4 anions in a plane as shown in figure. The 5th anion is in upper layer (coming outside the paper) and 6th in bottom layer (going in the paper).
Join cation anion centres E and B and complete ΔEBF
In ΔEBF
$m\angle F=90$, and EF=EB
$\therefore m\angle B=m\angle E=45$
where ra is radius of anion and rc is the radius of cation
and EB = ra + rc
and BF = ra
Therefore-
$cosB=cos45=\dfrac{r_a}{r_a}+r_c=0.7071$
$\dfrac{r_c}{r_a}=\dfrac{1-0.771}{0.7071}=0.414$
critical radius ratio of ionic crystal in ligacy 6 configuration is 0.414
When radius of anion is 2.02Å
$\dfrac{r_c}{2.02}=0.414$
rc = 0.836Å
Maximum size of cation in ligacy 6 configuration is 0.836Å in terms of radius.
ADD COMMENT
EDIT
Please log in to add an answer.