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Cu has FCC structure. If the interplanar spacing d is 2.08 A° for the set of (111) planes. Find the density and diameter of Cu atom. Give atomic weight of Cu is 63.54.
1 Answer
written 3.3 years ago by |
Given :-
Cu is FCC structure
interplanar distance (d) = 2.08 Aº
(hkl) = (111)
Atomic weight (A) = 63.54
To find :-
Density ($ { \rho}$)
Diameter
Formula:
$d =\dfrac {a}{\sqrt{h^2+k^2+l^2}}$
$2.08 = \dfrac{a}{ \sqrt{1^2+1^2+1^2}}$
$a = {2.08 \sqrt{3}}$ Aº
a = 3.603 Aº
As it is FCC structure (n = 4)
$a^3\rho = {n}$$({A\over N})$ $\rho = {n\over a^3}{( {A\over N})}$ $\rho = {4\over ( \sqrt {3}\times2.08\times10^{-10})^3}$${\times ({63.54\over6.023\times10^{26}})}$ $ = ({8.55\times10^{28} ) \times (1.05\times10^{-25}) }$ $Density(\rho)= {9.02 \times 10^3}$ For FCC $r= {a \sqrt{2} \over 4}$ Diameter (2r) = ${a \sqrt{2} \over 2}$
Diameter = 2.54 Aº