Dolomite is magnesium lime stone with the composition, $CaMg(CO_3)_2$
Properties:
- Dolomite bricks are more porous and possess more softness, shrinkage and less strength than magnesia bricks.
- They can be used upto 2300°C without load and upto 1650°C under a load of 3.5Kg/cm2
Preparation:
- Dolomite is calcined, powdered and mixed with binding material and water. Mixing is performed in edge runner and then allowed to age by keeping it in wet condition.
- The mixture is moulded to bricks which are air dried and burnt to a temperature ranging between 1200°C to 1650°C.
- For preparing stabilized dolomite bricks, dolomite is mixed with serpentine$(MgO\cdot SiO_2)$ and the mixture is calcined to form di- and tri-calcium silicates which do not absorb water and carbon dioxide.
- The calcined mixture is mixed with a binding agent (usually silicate) and moulded into bricks which when burnt at about 1500°C for about a day gives stabilized dolomite bricks.
Uses:
- It is generally used as a repairing material rather than as a direct refractory because of its defects like:
great porosity, shrinkage and softness.
- However, stabilized dolomite bricks are used in electric furnaces, bessemer convertors, open-hearth furnaces, etc and as a cheap substitute for magnesia bricks.