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To a 25 ml H2O2 solution excess of acidified solution of KI was added. The iodine liberated require 20 ml of 0.3(N)Na2S2O3 solution for complete reaction.

University Name > First Year Engineering > Semester > Physical Chemistry

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H2O2+2KI2KOH+I2

I2+2Na2S2O3Na2S4O6+2NaI

20 ml of 0.3(N)Na2S2O3=20×0.3×103 =6×103 moles moles of H2O2 present =3×103 mol. molarity of H2O2 solution = 3×10325×103 =325(M) the vol strength of H2O2 solution =325×11.2=1.344 vol

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