FE > Semester 1 > Applied Chemistry 1

Marks : 05

Years : DEC 2014

1. The maximum number of phases in a two component system will be four. Maximum number of phases exists when degree of freedom is zero

P = C – F + 2

= 2 – 0 + 2

= 4

1. Maximum degree of freedom in a 2 component system will be 3 when system exists as one phase

F = C – P + 2

= 2 – 1 + 2

= 3

1. System will have three variables namely temperature, pressure and concentration. For constructing a phase diagram of 2-component system, a three dimensional space model is required using these 3 variables as its coordinates.

2. It is possible to split such a 3D diagram into 2D by keeping the third variable in each case as constant.

1. It is convenient to prepare temperature – composition (T-C) diagrams keeping pressure constant, such diagrams are called Isobaric.

Similarly, P-C diagrams at constant temperature are called isothermal.

P-T diagrams at constant composition are called isoplethal.

1. Any such restriction in phase rule equation regarding constancy of one of the variables reduces the phase rule equation to following form –

F = C – P + 1

OR

F + P = C + 1

This is known as reduced phase rule equation