Crystal act as three dimensional grating with X-rays
- Since the wavelength of X-rays is in the order of 1 A^0 or 〖10〗^(-8) cm, ordinary grating which has 6000 lines per cm cannot produce an appreciable diffrac-tion pattern of X-rays.
- Therefore, in the case of X-rays, instead of ordinary grating crystals gratings are used. In crystal grating atoms are arranged at lattice points in a regular fashion.
- These arranged atoms correspond to grating lines and the distance between two atoms is the grating element, in the order of le cm.
- The crystal grating differs from optical grating in such a way that in crystal grating, the atomic centers are not in one plane but are distributed in 3-dimensional space. But in optical grating, they are limited to one plane.
- Hence, crystal act as three dimensional grating with X-rays
Problem
Given:
$λ=5.8189 A^0$
$Ѳ = 75.86^0$
Lattice constant = $a = 3A^0$
Find:
Miller indices
Solution:
According to Bragg’s law,
$λ= 2d sin Ѳ$
$5.8189= 2d sin 75.86$
$d=3.0003 A^0$
Now, for a cubic crystal the interplanar spacing d is related to the lattice constant a by the equation,
$d = \frac{a}{\sqrt{(h^2+k^2+l^2)}}$
$\sqrt{h^2+k^2+l^2} = \frac{a}{d} = \frac{3}{3.0003} = 0.99 ≈ 1$
This is possible only when one of h, k and l are equal to 1 and other two equal to zero.
Thus, the Miller indices for the reflecting planes are (1 0 0), (0 1 0), (0 0 1)