written 8.4 years ago by | modified 2.2 years ago by |
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Effects of alloying elements on phase transformations
written 8.4 years ago by | modified 2.2 years ago by |
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Effects of alloying elements on phase transformations
written 8.4 years ago by |
The transformations represented in the above diagram are denoted by phases A1, A2, A3, A4in steel region. These transformations can be reversed on cooling
Phase at temperature | Transformation |
---|---|
A1 at 727°C in pearlite phase | A2 <=910°C at Austenite phase FCC structure |
A3 Austenite FCC structure at 910°C, (α-ferrite) | A4 (γ-austenite )1400°C |
A4 (γ-austenite ) 1400°C | δ-ferrite BCC structure |
Austenite stabilizers such as Nickel, Manganese, Copper and Nitrogen tend to raise temperatures A4 temperature and lower A1 and A3 temperature as a result of which more austenite region is present in the above diagram as compared to ferrite region. These elements are more stable in austenite region of steel
Ferrite stabilizers such as Chromium, Tungsten, Vanadium, Molybdenum, Silicon and Aluminum more stable in ferrite region. By addition of these elements into the steel the proportion of ferrite region increases by reducing the area occupied by austenite region in the iron-iron equilibrium diagram. They raise A1 and A3 temperatures by lowering the A4 temperature as shown in diagram 2.