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Materials for substrates

Mumbai University > Electronics Engineering > Sem 8 > MEMS Technology

Marks: 5M

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  • Substrates in LIGA process must be electrical conductive to facilitate subsequent electroplating over photoresists mold.
  • Metals such as : steel copper plates, titanium and nickel, or
  • Silicon with thin titanium or silver / chrome top layer, glass with thin metal layers.

Photoresists materials

Basic requirements:

  • Must be sensitive to x-ray radiation.
  • Must have high resolution and resistance to dry and wet etching.
  • Must have thermal stability up to 1400C.
  • The unexposed part must be absolutely insoluble during development.
  • Good adhesion to substrate during electroplating.
  • PMMA appears most popular for LIGA process, but other polymers are available:
PMMA POM PAS PMI PLG
Sensitivity Bad Good Exellent Reasonable Reasonable
Resolution Exellent Reasonable Very bad Good Exellent
Sidewall smoothness Exellent Very bad Very bad Good Exellent
Stress corrosion Bad Excellent Good Very bad Exellent
Adhesion on substrate Good Good Good Bad Good

Electroplating

  • The inner surfaces of the photoresists mold produced by X-ray lithography need to be plated with thin metal layers for securing permanent microstructure geometry.
  • Metals available for the plating are: Ni, Cu, Au, NiFe and N/W.
  • In case of plating with Ni, the process is:
  • Nickel ions (Ni2+) are produced from electrolysis of NiCl2 solution.
  • They are attracted to the electrons at the cathode:
  • Ni2 + 2e $\rightarrow$ Ni
  • There could be H+ ions presence at the same cathode in the process.
  • These H+ ions may form H2 bubbles on the cathode, and thus Ni plate.
  • Proper control of the pH in the solution is important to miligate this effect.
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